Rhodium (Thiophosphinoyl)(trimethylsilyl) methanide and Bis (thiophosphinoyl) methanide Complexes: S~ S vs. C~ S Coordination

…, S Carenco, XF Le Goff, N Mézailles

Index: Heuclin, Hadrien; Carenco, Sophie; Le Goff, Xavier-Frederic; Mezailles, Nicolas European Journal of Inorganic Chemistry, 2012 , # 9 p. 1453 - 1461

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Abstract

Abstract A comparative study of the coordination modes of a (thiophosphinoyl)(trimethylsilyl) methanide (1–· Li+) and bis (thiophosphinoyl) methanide (2–· Li+) ligand with Rh I was carried out. Several complexes were synthesized and characterized. For 1–· Li+, C~ S coordination is forced, whereas for 2–· Li+, S~ S and C~ S coordination can be achieved. In one case, a dynamic equilibrium between these two modes of coordination was observed. ...

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