Reductive cleavage of the halogen–phosphorus and sulfur–phosphorus bonds with alkali metals

M Stankiewicz, J Nycz, J Rachon

Index: Stankiewicz, Marek; Nycz, Jacek; Rachon, Janusz Heteroatom Chemistry, 2002 , vol. 13, # 4 p. 330 - 339

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Citation Number: 9

Abstract

Abstract The reduction of thiophosphorus acid chlorides with alkali metals (Na, K) in liq. NH 3/THF solution, potassium anthracenide, and potassium naphthalenide was investigated. It was found that these types of phosphorus compounds easily undergo reduction to> P [ ...