Reactions of phenyltriazolinedione with alkenes. Stereochemistry of methanol adducts to aziridinium imide intermediates

…, IM Mavridis, A Pantidou, M Orfanopoulos

Index: Smonou, Ioulia; Khan, Saeed; Foote, Christopher S.; Elemes, Yiannis; Mavridis, Irene M.; Pantidou, Ariadne; Orfanopoulos, Michael Journal of the American Chemical Society, 1995 , vol. 117, # 27 p. 7081 - 7087

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Citation Number: 39

Abstract

Abstract: The addition of 4-phenyl-1, 2, 4-triazoline-3, 5-dione (PTAD) and the stereochemistry of methanol/PTAD adduct formation with cis-and truns-2-butenes, I- methylcyclopentene,(, 5')-2-methyl-2-butene-I, 1, I-d3, and substituted indenes (indene, 2- methylindene, 2, 3-dimethylindene) have been investigated. There is no loss of stereochemistry in the addition of MeOH and PTAD to butenes, 1-methylcyclopentene, 2- ...

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