Obsevations on the cleavage of the bismuth–carbon bond in Bi V compounds: a new arylation reaction

…, DJ Lester, WB Motherwell, MTB Papoula

Index: Barton, Derek H. R.; Lester, David J.; Motherwell, William B.; Papoula, M. Teresa Barros Journal of the Chemical Society, Chemical Communications, 1980 , # 5 p. 246 - 247

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Citation Number: 16

Abstract

Further examples of the selectivity of pentavalent trianyl-organobismuth oxidants are presented; deuterium labelling studies have established that the mechanism of oxidation of allylic alcohols by these reagents involves, to some extent, cleavage of the bismuth–aryl bond; several reactions involving the synthetically useful transfer of an aryl group from bismuth to nitrogen and to carbon are described.

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