Facile one-pot synthesis of S-alkyl thiocarbamates

JH Wynne, SD Jensen, AW Snow

Index: Wynne, James H.; Jensen, Samuel D.; Snow, Arthur W. Journal of Organic Chemistry, 2003 , vol. 68, # 9 p. 3733 - 3735

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Citation Number: 40

Abstract

Condensation of a thiol with an isocyanate affords the corresponding thiocarbamate; however, this route was only demonstrated when alkoxy and aroxysulfonyl isocyanates were employed. 6 Moreover, the hydration of a variety of organic thiocyanates has been reported to afford the desired compound in the presence of hydrogen chloride; however, this method is limited to only N,N-unsubstituted thiocarbamates. 19,20 N,N-Disubstituted S-alkyl ...