Acidities of polyfluorinated hydrocarbons. II. Hexafluoropropanes, trifluoroethanes, and haloforms. Intermediate carbanion stability and geometry

KJ Klabunde, DJ Burton

Index: Klabunde,K.J.; Burton,D.J. Journal of the American Chemical Society, 1972 , vol. 94, p. 5985 - 5990

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Citation Number: 39

Abstract

Abstract: Pseudo-first-order kinetic acidities have been determined for a series of 2- substituted 1, 1, 1, 3, 3, 3-hexafluoropropanes, 1, l, I-trifluoroethanes, and haloforms by hydrogen, deuterium, and tritium isotope exchange reactions. Techniques of '9F nmr, ir, and scintillation counting were used to determine these acidities. The solventcatalyst system employed was a 50: 50 mol solution of dimethyl sulfoxide and methanol with triethylamine ...