Electrolytic transformation of fluoroorganic compounds. 3. Highly regioselective anodic methoxylation of N-(2, 2, 2-trifluoroethyl) amines

T Fuchigami, Y Nakagawa…

Index: Fuchigami, Toshio; Nakagawa, Yuuki; Nonaka, Tsutomu Journal of Organic Chemistry, 1987 , vol. 52, # 24 p. 5489 - 5491

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Citation Number: 48

Abstract

Summary: Anodic methoxylation of N-alkyl-N-(2, 2, 2-trifluoroethy1) anilines and N-(2, 2, 2- trifluoroethyl) di-phenylamine places the methoxy group in the a-position (toward the trifluoromethyl group); these products are useful building blocks for the construction of a carboncarbon bond at this a-position.

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