Journal of Organometallic Chemistry

Metal derivatives of amidoximes V. Dialkyl-or diphenyl-silyl derivatives of amidoximes

AB Goel, VD Gupta

Index: Goel,A.B.; Gupta,V.D. Journal of Organometallic Chemistry, 1975 , vol. 85, p. 327 - 333

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Citation Number: 2

Abstract

Dial!@- or diphenyl-diethoxysilanes were refluxed with the amidoximes in l/2 molar ratio in benzene, in the presence of a small amount of sodium. The progress of the reaction was checked by estimating the liberated ethanol. ... R,Si(OEt), + 2 R'C(NH,)=NOH -9 R.$i[ON=C(R')NH,], + 2 EtOH ... Attempted preparation of mono-derivatives by carrying out the reactions in equimolar proportions invariably resulted in bis-products (I). These results are consistent with earlier ...