Medium effects on activation parameters on alkaline hydrolysis of 2-carbomethoxypropionate ion in aqueous mixtures of ethylene glycol

PK Biswas, BC Bag, MN Das

Index: Biswas, Prasanta Kumar; Bag, Bikas Chandra; Das, Mihir Nath Canadian Journal of Chemistry, 1987 , vol. 65, p. 235 - 237

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Citation Number: 2

Abstract

The standard free energies of transfer of the 2-carbomethoxypropionate ion (R-) have been determined from the solubilities of the silver salt (AgR) in water and six aqueous mixtures of ethylene glycol (1-60%) at 25° C, using the literature values of of Ag+. Utilizing these values of the R-ion as well as the literature values of of the OH-ion, combined with the experimental values of Δ G≠ for the alkaline hydrolysis of R-ion, the corresponding transfer parameters ...