Photochemical synthesis of 6, 7-dihydro-5H-dibenz [c, e] azepine and 5, 6, 7, 8-tetrahydrodibenz [c, e] azocine derivatives

PW Jeffs, JF Hansen, GA Brine

Index: Jeffs,P.W. et al. Journal of Organic Chemistry, 1975 , vol. 40, p. 2883 - 2890

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Citation Number: 31

Abstract

excess of dissolved ozone. The reaction was assumed to be complete and oxygen was passed through the mixture for 5 min to remove excess ozone. The solution became colorless. Methanol (25 ml) was then added and the mixture was left to stand at room temperature for 1 hr. Work-up involved the addition of 50 ml of water followed by solvent removal to give a yellow oil (750 mg, 70%). 24 This yellow oil exhibited no C= N stretching ...