The Oxychlorides of Silicon and the Corresponding Ethyl Esters

WC Schumb, DF Holloway

Index: Schumb, W. C.; Holloway, . F. Journal of the American Chemical Society, 1941 , vol. 63, p. 2753 - 2755

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Citation Number: 19

Abstract

The literature concerning the identity of the oxychlorides of silicon has been in a somewhat confused state since the original work of Friedel and Ladenburg'and of Troost and Hautefeuille. 2 The former investigators first prepared hexachlorodisiloxane, Si2OCl6, by passing the vapors of silicon tetrachloride through a porcelain tube packed with fragments of white-hot feldspar. The latter experimenters claimed to have prepared a series of ...