Tetrahedron

The fluoride ion effect in the reactions of singlet oxygen with enols

HH Wasserman, JE Pickett

Index: Wasserman, Harry H.; Pickett, James E. Tetrahedron, 1985 , vol. 41, # 11 p. 2155 - 2162

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Citation Number: 36

Abstract

The fluoride ion effect in the reactions of enolic systems with singlet oxygen has been investigated. β-Dicarbonyl compounds yielded 1, 2, 3-tricarbonyl derivatives, some of which underwent further hydration, whereas α-diketones suffered oxidative decarboxylation to give open-chain aldehydo-acids or keto-acids.

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