Synthesis

Highly selective and efficient catalyst for carbonylation of aryl iodides: Dimeric palladium complex containing carbon-palladium covalent bond

C Ramesh, Y Kubota, M Miwa, Y Sugi

Index: Ramesh, Chinnasamy; Kubota, Yoshihiro; Miwa, Minoru; Sugi, Yoshihiro Synthesis, 2002 , # 15 p. 2171 - 2173

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Citation Number: 14

Abstract

Abstract Dimeric cyclometallated oxime palladium complex containing palladium-carbon covalent bond was found to efficiently catalyze the carbonylation reactions of aryl iodides with various alcohols to give esters in excellent yields with high selectivity. These complexes were also stable under a carbon monoxide atmosphere at high temperatures.

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