Stereochemistry and regiochemistry of heteroatom directed reactions. 5. The first practical method of selective heteroatom-directed chlorohydroxylation

J Lai, F Wang, G Guangzhong…

Index: Lai, Jin-Yu; Wang, Fu-Song; Guo, Guang-Zhong; Dai, Li-Xin Journal of Organic Chemistry, 1993 , vol. 58, # 25 p. 6944 - 6946

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Abstract

Summary: A new Pd (I1)-catalyzed nucleophilic chlorohydroxylation reaction of allylic amines and sulfides was achieved, and the regioselective reaction gives high yields of the chlorohydrin products, which can be transformed into epoxy compounds or aziridine

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