Pulse-duration effects on competitive reactions in infrared multiple-photon decomposition of 1, 2-dichlorofluoroethane and 1, 2-dichloro-1, 2-difluoroethane

Y Ishikawa, K Sugita, S Arai

Index: Ishikawa, Yo-ichi; Sugita, Kyoko; Arai, Shigeyoshi Journal of Physical Chemistry, 1986 , vol. 90, # 21 p. 5067 - 5071

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Citation Number: 2

Abstract

Sum mary Rate constants for collisional quenching of D2CC (3B2) by Ar, N2, H2, CO, and CH4 have been measured for the first time, using vacuum-ultraviolet photolysis in conjunction with absorption spectroscopy techniques. Under our experimental conditions, no evidence of chemical quenching of vinylidene with these collision partners are observed.