Aliphatic semidiones. V. Radical anions derived from vicinal triketones
GA Russell, SA Weiner
Index: Russell,G.A.; Weiner,S.A. Journal of the American Chemical Society, 1967 , vol. 89, # 25 p. 6623 - 6628
Full Text: HTML
Citation Number: 18
Abstract
Abstract: Preparation and detection by esr spectroscopy of radical anions (semitriones) derived from CaH5COCOCOCaHs, CHaCOCOCOOR, and ROCOCOCOOR are described. In basic solution vicinal tri-or tetraketones have a great tendency to undergo decarbonylation to yield the a-diketone or its radical anion. These semitriones can be prepared only in the absence of strong base. The same degradation was observed for ...
Related Articles:
[Verhe,R. et al. Bulletin des Societes Chimiques Belges, 1978 , vol. 87, p. 143 - 152]
[Verhe,R. et al. Bulletin des Societes Chimiques Belges, 1978 , vol. 87, p. 143 - 152]
[Verhe,R. et al. Bulletin des Societes Chimiques Belges, 1978 , vol. 87, p. 143 - 152]
[Verhe,R. et al. Bulletin des Societes Chimiques Belges, 1978 , vol. 87, p. 143 - 152]
[Verhe,R. et al. Bulletin des Societes Chimiques Belges, 1978 , vol. 87, p. 143 - 152]