Cobalt (II) catalyzed oxidation of aldehydes to carboxylic acid with molecular oxygen
B Bhatia, J Iqbal
Index: Bhatia, Beena; Iqbal, Javed Tetrahedron Letters, 1992 , vol. 33, # 51 p. 7961 - 7964
Full Text: HTML
Citation Number: 10
Abstract
Abstract A variety of aromatic and some aliphatic aldehydes are efficiently transformed to the corresponding carboxylic acid in presence of catalytic amount of Cobalt (II) chloride, molecular oxygen and acetic anhydride at room temperature. Phenolic aldehydes undergo acylative oxidation to give the corresponding acylated carboxylic acid.
Related Articles:
[Gupta, Monika; Paul, Satya; Gupta, Rajive; Loupy, Andre Tetrahedron Letters, 2005 , vol. 46, # 30 p. 4957 - 4960]
[Dalpozzo, Renato; De Nino, Antonio; Maiuolo, Loredana; Oliverio, Manuela; Procopio, Antonio; Russo, Beatrice; Tocci, Amedeo Australian Journal of Chemistry, 2007 , vol. 60, # 1 p. 75 - 79]
[Babin, Pierre; Bennetau, Bernard Tetrahedron Letters, 2001 , vol. 42, # 31 p. 5231 - 5233]
[van Alphen Recueil des Travaux Chimiques des Pays-Bas, 1925 , vol. 44, p. 839]
[Bellezza, Francesca; Cipiciani, Antonio; Cruciani, Gabriele; Fringuelli, Francesco Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4439 - 4444]