Journal of Chemical Research

An efficient method for the preparation of β-nitroalkanols in room temperature ionic liquids

W Qian, F Ju, W Bao, Y Zhang

Index: Qian, Weixing; Ju, Fengyang; Bao, Weiliang; Zhang, Yongmin Journal of Chemical Research, 2004 , # 2 p. 154 - 155

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Citation Number: 1

Abstract

The Henry (nitroaldol) reaction is one of the most important methods for carbon–carbon formation. The adducts may be transformed into valuable building blocks. β-Nitroalkanols are particularly important precursors in the synthesis of nitro alkenes, β-amino alcohols and α-nitro ketones.1-5 Nitro alkenes have proved to be useful intermediates, which behave both as electron-deficient alkenes and as heterodienes in Diels–Alder reactions,6-7 while α-nitro ...