Palladium-nanoparticle-catalyzed 1, 7-palladium migration involving C–H activation, followed by intramolecular amination: regioselective synthesis of N 1- …

…, Y Shiro, H Fukuda, S Shuto, M Arisawa

Index: Hoshiya, Naoyuki; Shimoda, Masahiko; Yoshikawa, Hideki; Yamashita, Yoshiyuki; Shuto, Satoshi; Arisawa, Mitsuhiro Journal of the American Chemical Society, 2010 , vol. 132, # 21 p. 7270 - 7272

Full Text: HTML

Citation Number: 17

Abstract

A sulfur-modified gold-supported palladium material (SAPd) has been developed bearing palladium nanoparticles on its surface. Herein, we report for the first time the use of SAPd to affect a Pd-nanoparticle-catalyzed 1, 7-Pd migration reaction for the synthesis of benzotriazoles via C–H bond activation. The resulting benzotriazoles were evaluated in terms of their inhibitory activity toward indoleamine 2, 3-dioxygenase.

Related Articles:

Synthesis and applications of a new palladacycle as a high active catalyst in the Suzuki couplings

[Joshaghani, Mohammad; Daryanavard, Marzieh; Rafiee, Ezzat; Nadri, Shirin Journal of Organometallic Chemistry, 2008 , vol. 693, # 19 p. 3135 - 3140]

Suzuki coupling reaction catalyzed heterogeneously by Pd (salen)/polyoxometalate compound: another example for synergistic effect of organic/inorganic hybrid

[Tong, Jinhui; Wang, Haiyan; Cai, Xiaodong; Zhang, Qianping; Ma, Hengchang; Lei, Ziqiang Applied Organometallic Chemistry, 2014 , vol. 28, # 2 p. 95 - 100]

Palladium-bisimidazol-2-ylidene complexes as catalysts for general and efficient Suzuki cross-coupling reactions of aryl chlorides with arylboronic acids

[Zhang, Chunming; Trudell, Mark L. Tetrahedron Letters, 2000 , vol. 41, # 5 p. 595 - 598]

Versatile catalysts for the Suzuki cross-coupling of arylboronic acids with aryl and vinyl halides and triflates under mild conditions

[Littke, Adam F.; Dai, Chaoyang; Fu, Gregory C. Journal of the American Chemical Society, 2000 , vol. 122, # 17 p. 4020 - 4028]

A simple and efficient reusable polystyrene-supported palladium catalyst for Hiyama cross-coupling

[Diebold, Carine; Derible, Antoine; Becht, Jean-Michel; Le Drian, Claude Tetrahedron, 2013 , vol. 69, # 1 p. 264 - 267]

More Articles...