Phosphorus, Sulfur, and Silicon

Nouvelles voies d'acces aux 2-ethoxycarbonylallylphosphonates

H Mrabet, H Zantour

Index: Mrabet, Hedi; Zantour, Hedi Phosphorus, Sulfur and Silicon and the Related Elements, 2004 , vol. 179, # 1 p. 25 - 33

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Citation Number: 6

Abstract

The Michaelis-Arbusov reaction (method A) and the nucleophilic addition of dialkylphosphites followed by Hoffman olefination (method B) represent two synthetic methods giving a variety of 2-ethoxycarbonylallyl-phosphonates 2, in good yields, from readily accessible ethyl 2-(N, N-dialkylaminomethyl) acrylates 1.

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