Chemical and Pharmaceutical Bulletin

Phosphorylation by Active Ester of Phosphoric Acid. I. Preparation and Reaction of Phenyl 8-Quinolyl Phosphate

H TAKAKU, Y SHIMADA

Index: Takaku,H.; Shimada,Y. Chemical and Pharmaceutical Bulletin, 1973 , vol. 21, p. 445 - 447

Full Text: HTML

Citation Number: 6

Abstract

In the present study, the preparation of phenyl 8-quinolyl phosphate (4) and the reactions of the active diester of phosphoric acid (4) with alcohols and amines were investigated. It was considered that the phosphate (4) would yield a reactive intermediate (4'), which in turn would further react with alcohols to give diesters of phosphoric acid as shown in Chartl. The synthesis of diester of phosphoric acid can be effected successfully by this method since it ...

Related Articles:

A general method for the synthesis of O-alkyl N, O′-arylphosphoramidates and its application to the synthesis of a transition state analogue for carbamate hydrolysis

[Taylor, Scott D.; Chen, Mei-Jin; Dinaut, A. Nicole; Batey, Robert A. Tetrahedron, 1998 , vol. 54, # 17 p. 4223 - 4242]

Phosphoramidate solvolysis

[Oeney,I.; Caplow,M. Journal of the American Chemical Society, 1967 , vol. 89, p. 6972 - 6980]

Solvolysis of diphenyl amidophosphates in aqueous alcoholic media

[Kasparek, Frantisek; Mollin, Jiri Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 2 p. 386 - 396]

Solvolysis of diphenyl amidophosphates in aqueous alcoholic media

[Kasparek, Frantisek; Mollin, Jiri Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 2 p. 386 - 396]

More Articles...