Synthesis, structural elucidation and catalytic activity toward a model Mizoroki–Heck C–C coupling reaction of the pyrazolic Tröger's base Pd 4 Cl 8 (PzTB) 2 complex

F Cuenú, R Abonia, A Bolaños, A Cabrera

Index: Cuenu, Fernando; Abonia, Rodrigo; Bolanos, Alberto; Cabrera, Armando Journal of Organometallic Chemistry, 2011 , vol. 696, # 9 p. 1834 - 1839

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Citation Number: 7

Abstract

The synthesis of a novel palladium (II) complex Pd4Cl8 (PzTB) 2, where PzTB is a pyrazole Tröger's base analogue ligand is reported. A complete structure elucidation of the complex was achieved by spectroscopic and crystallographic data, exhibiting a metallomacrocycle supramolecular structure and a planar-square geometry on each palladium atom. This complex exhibited also a high activity and selectivity toward a model Mizoroki–Heck C–C ...

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