Catalytic deallylation of allyl-and diallylmalonates

D Necas, M Turský, M Kotora

Index: Necas, David; Tursky, Matyas; Kotora, Martin Journal of the American Chemical Society, 2004 , vol. 126, # 33 p. 10222 - 10223

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Citation Number: 58

Abstract

Substituted allylmalonates undergo the selective CC bond cleavage in the presence of triethylaluminum and a catalytic amount of nickel and ruthenium phosphine complexes, resulting in the loss of the allyl moiety and formation of monosubstituted malonates. Comparison of reactivity of the nickel and ruthenium complexes showed that the use of the former is general with respect to the structure of the substituted allylmalonates, and the ...

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