Aliphatic azo compounds. XVI. Stereoisomerization and homolytic decomposition of cis and trans bridgehead diazenes
M Schmittel, C Ruechardt
Index: Schmittel,M.; Rueckhardt,C. Journal of the American Chemical Society, 1987 , vol. 109, p. 2750
Full Text: HTML
Citation Number: 36
Abstract
Abstract: For a large series of bridgehead azo compounds, activation parameters for their homolytic decomposition and their cis-trans isomerization reactions are reported. In addition experimental heats of isomerization were obtained and compared with molecular mechanics calculations. It is concluded from a Bell-Evans-Polanyi plot that, in contrast to a previously made assumption, no change in mechanism within this series of trans-azo ...
Related Articles:
[Chae, Woo-Ki; Baughman, Sharon A.; Engel, Paul S.; Bruch, Manfred; Oezmeral, Cenan; et al. Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4824 - 4833]
[Severn,D.J.; Kosower,E.M. Journal of the American Chemical Society, 1969 , vol. 91, p. 1710 - 1717]
[Chae, Woo-Ki; Baughman, Sharon A.; Engel, Paul S.; Bruch, Manfred; Oezmeral, Cenan; et al. Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4824 - 4833]