Rate constants for the reactions of tris (trimethylsilyl) silyl radicals with organic halides
C Chatgilialoglu, D Griller…
Index: Chatgilialoglu, C.; Griller, D.; Lesage, M. Journal of Organic Chemistry, 1989 , vol. 54, # 10 p. 2492 - 2494
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Citation Number: 58
Abstract
This constraint was only a significant limitation for the least reactive halides used in this work. In these cases, competition experiments coupled with product analyses were used to tie the reactivities of the less labile materials to the absolute rate constants measured by the flash photolysis approach.
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