Aromatic thiocyanation using supported copper (I) thiocyanate

JH Clark, CW Jones, CVA Duke…

Index: Clark, James H.; Jones, Craig W.; Duke, Catherine V. A.; Miller, Jack M. Journal of the Chemical Society, Chemical Communications, 1989 , # 2 p. 81 - 82

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Citation Number: 12

Abstract

Aromatic thiocyanates may be prepared by several different methods, the most common of which is conversion of the diazotised primary aromatic amines with metal thiocyanatesl although the activating effect of the diazonium group may lead to displacement of another substituent in the molecule.2 The major problem with thiocyanations is the production of the corresponding, thermodynamically more stable isothio- cyanate, often in appreciable quantities.' It has been reported that ...