Chemistry Letters

The reaction of trimethylstannylmethyllithium with electrophiles

E Murayama, T Kikuchi, K Sasaki, N Sootome, T Sato

Index: Murayama, Eigoro; Kikuchi, Toshihiro; Sasaki, Kotaro; Sootome, Norio; Sato, Tadashi Chemistry Letters, 1984 , p. 1897 - 1900

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Citation Number: 1

Abstract

1898 Chemistry Letters, 19 8 4 Table 1. Methylenation of Carbonyl Compounds h „ , л , Yields of Carbonyl compounds olefins/^ that the use of octane as a solvent, instead of the no-solvent procedure in the original report, was advisable for a larger scale preparation. The treatment of 1 with methyllithium produced 2, which was directly used for further reaction. When n-butyllithium was used instead of methyllithium, the product was contaminated by a butyl derivative J3, ...

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