Reaction of Silyl (carbonyl) iron Complexes with LiAlH_4 Giving Methylsilanes: Reduction of a Carbonyl Ligand and Coupling with a Silyl Group

H Tobita, R Shiozawa, H Ogino

Index: Tobita, Hiromi; Shiozawa, Rie; Ogino, Hiroshi Chemistry Letters, 1997 , # 8 p. 805 - 806

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Citation Number: 3

Abstract

抄録 Treatment of CpFe (CO)< SUB> 2 SiR< SUB> 3(R< SUB> 3=(< SUP>< I> p Tol)< SUB> 2 H,(< SUP>< I> p Tol)< SUB> 2 Me, MePh (1-Nap); 1-Nap= 1-naphthyl) with LiAlH< SUB> 4 in ether or THF at room temperature gave CH< SUB> 3 SiR< SUB> 3 as a major product in moderate to high yield. The labeling experiments using LiAlD< SUB> 4 and CpFe ...