Effective alkoxylation of phosphorescent heteroleptic iridium (III) compounds bearing fluorinated bipyridine ligands

H Oh, KM Park, H Hwang, S Oh, JH Lee, JS Lu…

Index: Oh, Chan Seok; Lee, Chil Won; Lee, Jun Yeob Chemical Communications, 2013 , vol. 49, # 37 p. 3875 - 3877

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Citation Number: 24

Abstract

Facile one-pot synthetic methods for new alkoxo-functionalized heteroleptic cyclometalated Ir (III) compounds have been developed. Nucleophilic substitution of fluorine atoms in [(dfpypy) 2Ir (μ-Cl)] 2 (dfpypy= 2′, 6′-difluoro-2, 3′-bipyridine) by a methoxyethanol in the