Electronic effects in the reaction of carbonyl oxides with aldehydes

RW Murray, MM Morgan

Index: Murray, Robert W.; Morgan, Michael M. Journal of Organic Chemistry, 1991 , vol. 56, # 2 p. 684 - 687

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Citation Number: 18

Abstract

Electronic effects in the third step of the Criegee mechanism of ozonolysis, ie, the reaction of a carbonyl oxide with a carbonyl compound, were studied by using a non-ozone wurce of carbonyl oxides as well as by an ozonolysis method. Benzophenone oxide, produced by photosensitized oxidation of diphenyldiazomethane or ozonolysis of tetraphenylethylene, was reacted with a series of para-substituted benzaldehydes. The relative rates of triaryl ...