Synthesis

Palladium (0)-catalyzed silylation of aryl halides with triorganosilanes: Synthesis of aryl (2-furyl) silanes

…, H Ohara, R Oiwa, S Watanabe, Y Masuda

Index: Murata, Miki; Ohara, Hiroya; Oiwa, Ryo; Watanabe, Shinji; Masuda, Yuzuru Synthesis, 2006 , # 11 p. 1771 - 1774

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Abstract

Abstract Triorganosilanes, which possess two aryl groups on the silicon atom, undergo palladium-catalyzed silylation of aryl iodides. Aryl (2-furyl) silanes thus obtained are potentially useful starting materials for carbon-carbon bond-forming reactions in the presence of transition-metal catalysts and tetrabutylammonium fluoride.

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