How Do Analogous α-Chloroenamides and α-Iodoenamides Give Different Product Distributions in 5-Endo Radical Cyclizations?

DP Curran, DB Guthrie, SJ Geib

Index: Tamura, Osamu; Matsukida, Hana; Toyao, Atsushi; Takeda, Yoshifumi; Ishibashi, Hiroyuki Journal of Organic Chemistry, 2002 ,  vol. 67,  # 16  p. 5537 - 5545

Full Text: HTML

Citation Number: 32

Abstract

... Journal of the ... Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260. J. Am. ... Along these lines, Ishibashi and co-workers postulated that chloride 1a might have a ground-state preference for E-amide rotamer 1aE (Figure 3), and thus its derived radical ...