Journal of the American Chemical Society

Reaction of lithium N-isopropylcyclohexylamide with esters. Method for the formation and alkylation of ester enolates

MW Rathke, A Lindert

Index: Rathke,M.W.; Lindert,A. Journal of the American Chemical Society, 1971 , vol. 93, # 9 p. 2318 - 2320

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Citation Number: 193

Abstract

50 45 50 75 70 60 70 60 a The ester (10 mmol) was added to a 1.0 M solution of LiICA (10 mmol) in tetrahydrofuran at a temperature of-78", except where noted. Determined by glpc analysis of aliquots quenched with deuterium oxide. c Determined by proton nmr examination of ester recovered by preparative glpc from the quenched solutions (in a number of cases, the ester was examined in a crude state by simple evaporation of the ...

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