Bulletin of the Chemical Society of Japan

Bromochlorination of Alkenes with Dichlorobromate (1–) Ion. I

T Negoro, Y Ikeda

Index: Negoro; Ikeda Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 8 p. 2111 - 2115

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Citation Number: 25

Abstract

In the reaction of styrene with chlorine, the added bromide ions were mostly incorporated into the adduct, giving a bromo chloro compound. Tetrabutylammonium dichlorobromate (1– ) was found to be an efficient bromochlorinating agent. The reactions of 2-butenes and stilbenes were completely anti stereospecific.

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