Hydroxycarbonylation of isobutylene in the presence of the palladium acetylacetonate-triphenylphosphine-p-toluenesulfonic acid catalyst system

…, EG Chepaikin, GZ Zhaksylykova, KS Kanybetov…

Index: Suerbaev; Chepaikin; Zhaksylykova, G. Zh.; Kanybetov; Turkbenov; Abyzbekova Petroleum Chemistry, 2008 , vol. 48, # 3 p. 206 - 209

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Abstract

Abstract The reaction of isobutylene hydroxycarbonylation with carbon monoxide and an alcohol (ethanol, 1-menthol) in the presence of the palladium acetylacetonate- triphenylphosphine-p-toluenesulfonic acid catalytic system was investigated. It was shown that the reaction proceeds regioselectively with the formation of linear products (ethyl isovalerate, 1-menthyl isovalerate). The optimum conditions for running the process were ...

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