Coordination??Driven Hierarchical Organization of π??Conjugated Systems: From Molecular to Supramolecular π??Stacked Assemblies

Y Yao, W Shen, B Nohra, C Lescop…

Index: Yao, Yishan; Shen, Wenting; Nohra, Brigitte; Lescop, Christophe; Reau, Regis Chemistry - A European Journal, 2010 , vol. 16, # 24 p. 7143 - 7163

Full Text: HTML

Citation Number: 28

Abstract

Abstract The reaction of U-shaped, bimetallic, Cu I complexes, assembled from a heteroditopic pincer, with cyano-capped π-conjugated linkers gives a straightforward access to π-stacked metallocyclophanes in good yields. In these assemblies, the π-walls have an almost face-to-face arrangement. The versatility of this rational supramolecular synthesis is demonstrated with the use of linkers that have nanoscale lengths (up to 27.7 Å), different ...

Related Articles:

Synthesis of stilbenes via homocoupling of aryl aldehyde tosylhydrazones

[Kabalka, George W; Wu, Zhongzhi; Ju, Yuhong Tetrahedron Letters, 2001 , vol. 42, # 29 p. 4759 - 4760]

Evaluation of the selectivity of the epoxidation of cis-versus trans-alkenes by oxo [meso-tetrakis (2, 6-dibromophenyl) porphinato] chromium (V). Dynamics, products, …

[He, Gong-Xin; Mei, Houng-Yau; Bruice, Thomas C. Journal of the American Chemical Society, 1991 , vol. 113, # 15 p. 5644 - 5650]

Iodine atom-catalysed isomerisation of symmetrically substituted cis-stilbenes

[Muizebelt,W.J.; Nivard,R.J.F. Journal of the Chemical Society [Section] B: Physical Organic, 1968 , p. 913 - 920]

Reaktionen des Hexachlordibenzyls

[Weis,C.D. Helvetica Chimica Acta, 1966 , vol. 49, p. 234 - 243]

More Articles...