Chemische Berichte

Auf dem Wege zum Silaethen Me2Si C (SiMe3) 21): Trisilylierte Methane (Me3Si) 2 (Me2XSi) CY (X z. B. Hal, RO, RS; Y z. B. Br, Li)

N Wiberg, G Preiner, O Schieda

Index: Wiberg, Nils; Preiner, Gerhard; Schieda, Oswald Chemische Berichte, 1981 , vol. 114, # 6 p. 2087 - 2103

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Citation Number: 35

Abstract

Abstract Bromtrisilylmethane (Me 3 Si) 2 (Me 2 XSi) CBr (1–15) entstehen durch Reaktion von (Me 3 Si) 2-(Me 2 PhSi) CBr (16) mit Iodchlorid, Brom bzw. Iod (X [DOUBLE BOND] Cl, Br, I) sowie durch Reaktion von (Me 2 Si) 2 (Me 2 BrSi) CBr (1) mit AgX (X= F, p-TolSo 2, p- TolSo 3 MesSO 3, Ph 2 PO 2, Ph 2 PO 3, Ph 2 PO 4) oder MX (M= H, Li, Na; X= HO, RO, RS, Bu, Ph). Butyl-bzw. Phenyllithium vermag die Bromtrisilylmethane 1–16 bei tiefen ...

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