Fluoroolefin condensation catalyzed by aluminum chlorofluoride

CG Krespan, DA Dixon

Index: Krespan, Carl G.; Dixon, David A. Journal of Fluorine Chemistry, 1996 , vol. 77, # 2 p. 117 - 126

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Citation Number: 45

Abstract

High-fluorine-content aluminum chlorofluoride, as prepared by Cl/F exchange of aluminum chloride with one of a number of organofluorine compounds, is a very active Lewis acid capable of condensing an allylic fluoride with another fluoroolefin at low temperature. In addition to a description of broader scope, details of the selective reaction of hexafluoropropene with tetrafluoroethylene to form F-pentene-2 are presented along with ...