Magnesium-aluminium alkoxides: The synthesis of Mg [Al (OR) 4] 2 (R= Bu sec and Ph), structure of (thf) 2 Mg [(μ-OPh) 2 Al (OPh) 2] 2, and dynamic NMR of Mg [Al ( …

JA Meese-Marktscheffel, RE Cramer, JW Gilje

Index: Meese-Marktscheffel, Juliane A.; Cramer, Roger E.; Gilje, John W. Polyhedron, 1994 , vol. 13, p. 1045 - 1050

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Citation Number: 22

Abstract

Abstract Magnesium reacts with 2 equivalents of Al (OR) 3 and 2 equivalents of HOR, R= Bu sec or Ph, yielding Mg [Al (OBu sec 4] 2, a liquid which can be distilled under reduced pressure, or (thf) 2 Mg [(μ-OPh) 2 Al (OPh) 2] 2, a crystalline solid. An X-ray structure for (thf) 2 Mg [(μ-OPh) 2 Al (OPh) 2] 2 shows a distorted octahedral magnesium which is attached to two thf ligands and two Al (OPh) 4− chelates via double OPh bridges. Mass spectra ...