Journal of the American Chemical Society

Kinetics and mechanism of aliphatic amine oxidation by aqueous (batho) 2CuII

F Wang, LM Sayre

Index: Wang, Fengjiang; Sayre, Lawrence M. Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 248 - 255

Full Text: HTML

Citation Number: 64

Abstract

Abstract: The kinetics of oxidation of a large series of aliphatic amines by the “high-potential” oxidant (batho), Cu”(batho= 2, 9-dimethyl-4, 7-diphenyl-1, lO-phenanthrolinedisulfonate) was studied under pseudo-first-order conditions (excess amine) in water or in 30% aqueous methanol (v/v) at 25 'C over the pH range 7-1 1. The oxidations follow bell-shaped pH-rate profiles, with the low-pH leg reflecting the fact that only the free amine base is subject to ...

Related Articles:

Diphosphino-functionalised MCM-41-supported palladium complex: an efficient and recyclable catalyst for the formylation of aryl halides

[Jiang, Jianwen; Wang, Pingping; Cai, Mingzhong Journal of Chemical Research, 2014 , vol. 38, # 4 p. 218 - 222]

Application of flow chemistry to the reduction of nitriles to aldehydes

[Munoz, Juan De M.; Alcazar, Jesus; De La Antonio, Hoz; Diaz-Ortiz, Angel Tetrahedron Letters, 2011 , vol. 52, # 46 p. 6058 - 6060]

Introduction of N-sulfonic acid poly (4-vinylpyridinum) chloride as an efficient and reusable catalyst for the chemoselective 1, 1-diacetate protection and deprotection of …

[Shirini, Farhad; Jolodar, Omid Goli Journal of Molecular Catalysis A: Chemical, 2012 , vol. 356, p. 61 - 69]

Palladium-catalyzed formylation of organic halides with carbon monoxide and tin hydride

[Baillargeon,V.P.; Stille,J.K. Journal of the American Chemical Society, 1986 , vol. 108, p. 452]

Oxidation of benzyl alcohol and styrene using H 2 O 2 catalyzed by tetraazamacrocycle complexes of Cu (II) and Ni (II) encapsulated in zeolite-Y

[Bansal, Vipin Kumar; Thankachan, Pompozhi Protasis; Prasad, Rajendra Applied Catalysis A: General, 2010 , vol. 381, # 1-2 p. 8 - 17]

More Articles...