Some perfluoroalkylsulfinyl halides. New preparations of trifluoromethylsulfur trifluoride

CT Ratcliffe, JM Shreeve

Index: Ratcliffe,C.T.; Shreeve,J.M. Journal of the American Chemical Society, 1968 , vol. 90, p. 5403 - 5408

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Citation Number: 48

Abstract

Abstract: The reaction of CF3SCl with CFlOF is the superior of four new methods for the preparation of CF3SF3. Trifluoromethylsulfmyl fluoride, which is prepared in good yield by the controlled hydrolysis of CF3SF3, undergoes metathetical reactions with HX to give new compounds, CF3S (0) X. Trifluoromethylsulfinyl chloride and trifluoromethylsulfinyl bromide are prepared by reactions of CFsS (0) F with HCl and HBr, respectively. These tend to ...

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