Synthesis and reactivity of aldehydes of the adamantane series

SN Voloboev, LN Butenko, IA Novakov

Index: Voloboev; Butenko; Novakov Russian Journal of General Chemistry, 2001 , vol. 71, # 7 p. 1121 - 1125

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Abstract

Abstract 1-Adamantanecarbonitriles are very active in the Stephen reaction, which allows synthesis of the corresponding aldehydes in high yields. Electron-acceptor substituents in the 3 position of the adamantine nucleus exert almost no effect on the yield of aldehydes. Separation of the nitrile group and the adamantane nucleus by one methylene group results in a complete loss of reactivity. A quantitative study of the reactivity of the synthesized ...

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