Organic letters

[(CyPF-t Bu) PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides

Q Shen, JF Hartwig

Index: Shen, Qilong; Hartwig, John F. Organic Letters, 2008 , vol. 10, # 18 p. 4109 - 4112

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Citation Number: 78

Abstract

An air-and moisture-stable palladium catalyst,[(CyPF-t Bu) PdCl2](1), for coupling of heteroaryl chlorides, bromides, and iodides with a variety of primary amines is described. Most of these reactions occurred in high yield with 0.001− 0.05 mol% catalyst loading. The reactions tolerated a wide range of functional groups.

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