Acetylenic ethers. II. Ethoxy-and butoxy-acetylene

TL Jacobs, R Cramer, JE Hanson

Index: Jacobs; Cramer; Hanson Journal of the American Chemical Society, 1942 , vol. 64, p. 225

Full Text: HTML

Citation Number: 21

Abstract

Bromoalkoxyethylenes were prepared by the action of zinc and alcohol on dibromoacetals in the same way that alkenes are obtained from P-bromoether~.~ When the starting material was the dibutyl acetal, a mixed acetal of monobromoacetaldehyde, BrCH2CH (OC2Hb) OC4H9, was obtained as a by-product, apparently by the addition of a molecule of alcohol to bromobutoxyethylene. When a large run was attempted this mixed acetal was the ...

Related Articles:

Influence of the functionalization degree of acidic ion-exchange resins on ethyl octyl ether formation

[Guilera, Jordi; Hankova, Libuse; Jerabek, Karel; Ramirez, Eliana; Tejero, Javier Reactive and Functional Polymers, 2014 , vol. 78, # 1 p. 14 - 22]

Upgrading of the acid-rich fraction of bio-oil by catalytic hydrogenation-esterification

[Onyestyak, Gyoergy; Harnos, Szabolcs; Klebert, Szilvia; Stolcova, Magdalena; Kaszonyi, Alexander; Kallo, Denes Applied Catalysis A: General, 2013 , vol. 464-465, p. 313 - 321]

Hydrosilylation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η1-Silane Iridium (III) Complex

[Park, Sehoon; Brookhart, Maurice Organometallics, 2010 , vol. 29, # 22 p. 6057 - 6064]

Self??Optimizing Continuous Reactions in Supercritical Carbon Dioxide

[Parrott, Andrew J.; Bourne, Richard A.; Akien, Geoffrey R.; Irvine, Derek J.; Poliakoff, Martyn Angewandte Chemie - International Edition, 2011 , vol. 50, # 16 p. 3788 - 3792]

More Articles...