Facile synthesis of ethyl 2-arylpropenoates by cross-coupling reaction using electrogenerated highly reactive zinc
AA Jalil, N Kurono, M Tokuda
Index: Jalil, Aishah A; Kurono, Nobuhito; Tokuda, Masao Tetrahedron, 2002 , vol. 58, # 37 p. 7477 - 7484
Full Text: HTML
Citation Number: 47
Abstract
Highly reactive zinc metal was prepared by electrolysis of a DMF solution containing naphthalene and a supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a zinc anode. This reactive zinc was used for efficient transformation of ethyl 2- bromoacrylate into the corresponding organozinc compound, which was reacted with various aryl iodides or bromides in the presence of 5mol% Pd (P (o-Tol) 3) 2Cl2 to give ...
Related Articles:
[Shirai, Junya; Yoshikawa, Takeshi; Yamashita, Masayuki; Yamamoto, Yasuharu; Kawamoto, Makiko; Tarui, Naoki; Kamo, Izumi; Hashimoto, Tadatoshi; Ikeura, Yoshinori Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 21 p. 6430 - 6446]
[Jefford, Charles W.; Zaslona, Alexander Tetrahedron Letters, 1985 , vol. 26, # 49 p. 6035 - 6038]
[Mahmood, Syed J.; Brennan, Courtney; Mahmun Hossain Synthesis, 2002 , # 13 p. 1807 - 1809]
[Berthiol, Florian; Doucet, Henri; Santelli, Maurice European Journal of Organic Chemistry, 2003 , # 6 p. 1091 - 1096]
[Zadrozna; Kurkowska; Makuch Synthetic Communications, 1997 , vol. 27, # 23 p. 4181 - 4191]