Copper-catalyzed solvent-free redox condensation of benzothiazoles with aldehydes or benzylic alcohols
M Zhang, WT Lu, W Ruan, HJ Zhang, TB Wen
Index: Zhang, Mingliang; Lu, Wen-Ting; Ruan, Wenqing; Zhang, Hui-Jun; Wen, Ting-Bin Tetrahedron Letters, 2014 , vol. 55, # 10 p. 1806 - 1809
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Citation Number: 3
Abstract
Abstract An efficient and practical method for the construction of 2-aryl-and 2-alkyl- substituted benzothiazoles via a copper-catalyzed redox condensation process between benzothiazoles and aldehydes or benzylic alcohols has been developed. The reaction proceeded under mild reaction conditions using environmentally benign tert-butyl hydroperoxide (TBHP) as the oxidant. A reaction mechanism involving the ring-opening of ...
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