Synlett

A catalytic method for the reduction of secondary and tertiary phosphine oxides

M Berthod, A Favre-Réguillon, J Mohamad, G Mignani…

Index: Berthod, Mikael; Favre-Reguillon, Alain; Mohamad, Jahjah; Mignani, Gerard; Docherty, Gordon; Lemaire, Marc Synlett, 2007 , # 10 p. 1545 - 1548

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Citation Number: 35

Abstract

Transition-metal complexes incorporating phosphines and diphosphines as the ligands are frequently used catalysts in hydrogenation, hydroformylation, hydrocyanation, allylic substitution, hydrosilylations, and palladium- and nickel-catalysed coupling reactions. [1] The reduction of phosphine oxides in the final stage of a synthetic route constitutes a widely used synthesis of phosphine ligands. Indeed, because of the ease of interconversion of phosphine oxides ...

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