Chemical Communications

Efficient coupling reactions of allylamines with soft nucleophiles using nickel-based catalysts

H Bricout, JF Carpentier, A Mortreux

Index: Bricout, Herve; Carpentier, Jean-Francois; Mortreux, Andre Chemical Communications, 1997 , # 15 p. 1393 - 1394

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Citation Number: 18

Abstract

Substitution reactions of N, N-diethylallylamine 1 with soft nucleophiles such as active methylene compounds 2a–c and piperidine 5 proceed much more rapidly in the presence of Ni (dppb) 2 [dppb= 1, 4-bis (diphenylphosphino) butane] as catalyst than with comparable palladium systems.

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