Synthesis and preliminary physical properties of new neutral tetraalkoxy-substituted nickel bis (1, 2-dithiolene) complexes

…, B Garreau-de Bonneval, KIMC Ching

Index: Bui, Thanh-Tuan; Garreau-De Bonneval, Benedicte; Moineau-Chane Ching, Kathleen I. New Journal of Chemistry, 2010 , vol. 34, # 2 p. 337 - 347

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Citation Number: 17

Abstract

Nineteen neutral nickel bisdiphenylethenedithiolene complexes [Ni (dpedt) 2], including seventeen new compounds, were synthesized and characterized by a new short, efficient and multigram-scale synthetic method. Preliminary physical investigations show that these complexes are electron-withdrawing materials exhibiting good thermal stability and high molecular absorption coefficient in the near-infrared spectral region. Electrochemical and ...