N??Trialkylsilylimines as Coupling Partners for Pd??Catalyzed C N Bond??Forming Reactions: One??Step Synthesis of Imines and Azadienes from Aryl and Alkenyl …

J Barluenga, F Aznar, C Valdes

Index: Barluenga, Jose; Aznar, Fernando; Valdes, Carlos Angewandte Chemie - International Edition, 2004 , vol. 43, # 3 p. 343 - 345

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Citation Number: 72

Abstract

The palladium-catalyzed amination of aryl halides, known as the Buchwald–Hartwig reaction, has become a widely employed method in recent years for the synthesis of aryl amines.[1] The broad scope of this CÀN bond-forming reaction allows its application with a variety of both reactants, the halide and the nitrogen source. In fact, very efficient catalytic combinations have been uncovered for the coupling of amines with aryl and heteroaryl ...

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